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            CemicalBook

            Risk Phrases

            Indication of Particular Risks

            R1: Explosive when dry
            2: Risk of explosion by shock, friction, fire or other sources of ignition
            3: Extreme risk of explosion by shock, friction, fire or other sources of ignition
            4: Forms very sensitive explosive metallic compounds
            5: Heating may cause an explosion
            6: Explosive with or without contact with air
            7: May cause fire
            8: Contact with combustible material may cause fire
            9: Explosive when mixed with combustible material
            10: Flammable
            11: Highly Flammable
            12: Extremely Flammable
            14: Reacts violently with water
            15: Contact with water liberates extremely flammable gases
            16: Explosive when mixed with oxidizing substances
            17: Spontaneously flammable in air
            18: In use may form flammable/explosive vapor-air mixture
            19: May form explosive peroxides
            20: Harmful by inhalation
            21: Harmful in contact with skin
            22: Harmful if swallowed
            23: Toxic by inhalation
            24: Toxic in contact with skin
            25: Toxic if swallowed
            26: Very Toxic by inhalation
            27: Very Toxic in contact with skin
            28: Very Toxic if swallowed
            29: Contact with water liberates toxic gas
            30: Can become highly flammable in use
            31: Contact with acids liberates toxic gas
            32: Contact with acids liberates very toxic gas
            33: Danger of cumulative effects
            34: Causes burns
            35: Causes severe burns
            36: Irritating to the eyes
            37: Irritating to the respiratory system
            38: Irritating to the skin
            39: Danger of very serious irreversible effects
            40: Limited evidence of a carcinogenic effect
            41: Risk of serious damage to eyes
            42: May cause sensitization by inhalation
            43: May cause sensitization by skin contact
            44: Risk of explosion if heated under confinement
            45: May cause cancer
            46: May cause heritable genetic damage
            48: Danger of serious damage to health by prolonged exposure
            49: May cause cancer by inhalation
            50: Very Toxic to aquatic organisms
            51: Toxic to aquatic organisms
            52: Harmful to aquatic organisms
            53: May cause long-term adverse effects in the aquatic environment
            54: Toxic to flora
            55: Toxic to fauna
            56: Toxic to soil organisms
            57: Toxic to bees
            58: May cause long-term adverse effects in the environment
            59: Dangerous for the ozone layer
            60: May impair fertility
            61: May cause harm to the unborn child
            62: Possible risk of impaired fertility
            63: Possible risk of harm to the unborn child
            64: May cause harm to breast-fed babies
            65: Harmful: May cause lung damage if swallowed
            66: Repeated exposure may cause skin dryness or cracking
            67: Vapors may cause drowsiness and dizziness
            68: Possible risk of irreversible effects

            Risk Phrases

            Combination of Particular Risks

            14/15: Reacts violently with water, liberating extremely flammable gases
            15/29: Contact with water liberates toxic, extremely flammable gas
            20/21: Harmful by inhalation and in contact with skin
            20/21/22: Harmful by inhalation, in contact with skin and if swallowed
            20/22: Harmful by inhalation and if swallowed
            21/22: Harmful in contact with skin and if swallowed
            23/24: Toxic by inhalation and in contact with skin
            23/24/25: Toxic by inhalation, in contact with skin and if swallowed
            23/25: Toxic by inhalation and if swallowed
            24/25: Toxic in contact with skin and if swallowed
            26/27: Very Toxic by inhalation and in contact with skin
            26/27/28: Very Toxic by inhalation, in contact with skin and if swallowed
            26/28: Very Toxic by inhalation and if swallowed
            27/28: Very Toxic in contact with skin and if swallowed
            36/37: Irritating to eyes and respiratory system
            36/37/38: Irritating to eyes, respiratory system and skin
            36/38: Irritating to eyes and skin
            37/38: Irritating to respiratory system and skin
            39/23: Toxic: danger of very serious irreversible effects through inhalation
            39/23/24: Toxic: danger of very serious irreversible effects through inhalation in contact with skin
            39/23/24/25: Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
            39/23/25: Toxic: danger of very serious irreversible effects through inhalation and if swallowed
            39/24: Toxic: danger of very serious irreversible effects in contact with skin
            39/24/25: Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
            39/25: Toxic: danger of very serious irreversible effects if swallowed
            39/26: Very Toxic: danger of very serious irreversible effects through inhalation
            39/26/27: Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skin
            39/26/27/28: Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
            39/26/28: Very Toxic: danger of very serious irreversible effects through inhalation and if swallowed
            39/27: Very Toxic: danger of very serious irreversible effects in contact with skin

            39/27/28:

            Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
            39/28: Very Toxic: danger of very serious irreversible effects if swallowed
            42/43: May cause sensitization by inhalation and skin contact
            48/20: Harmful: danger of serious damage to health by prolonged exposure through inhalation
            48/20/21: Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
            48/20/21/22: Harmful: danger of serious damage to health by prolonged exposure through inhalation, and in contact with skin and if swallowed
            48/20/22: Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
            48/21: Harmful: danger of serious damage to health by prolonged exposure in contact with skin
            48/21/22: Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
            48/22: Harmful: danger of serious damage to health by prolonged exposure if swallowed
            48/23: Toxic: danger of serious damage to health by prolonged exposure through inhalation
            48/23/24: Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
            48/23/24/25: Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed
            48/23/25: Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
            48/24: Toxic: danger of serious damage to health by prolonged exposure in contact with skin
            48/24/25: Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
            48/25: Toxic: danger of serious damage to health by prolonged exposure if swallowed
            50/53: Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
            51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
            52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
            68/20: Harmful: possible risk of irreversible effects through inhalation
            68/20/21: Harmful: possible risk of irreversible effects through inhalation and in contact with skin
            68/20/21/22: Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
            68/20/22: Harmful: possible risk of irreversible effects through inhalation and if swallowed
            68/22: Harmful: possible risk of irreversible effects if swallowed
            68/21: Harmful: possible risk of irreversible effects in contact with skin
            68/21/22: Harmful: possible risk of irreversible effects in contact with skin and if swallowed
            68/22: Harmful: possible risk of irreversible effects if swallowed

            Safety Phrases

            Indication of Safety Precautions

            S1: Keep locked up
            2: Keep out of the reach of children
            3: Keep in a cool place
            4: Keep away from living quarters
            5: Keep contents under ... (appropriate liquid to be specified by the manufacturer)
            6: Keep under ... (inert gas to be specified by the manufacturer)
            7: Keep container tightly closed
            8: Keep container dry
            9: Keep container in a well-ventilated place
            12: Do not keep the container sealed
            13: Keep away from food, drink and animal feeding stuffs
            14: Keep away from ... (incompatible materials to be indicated by the manufacturer)
            15: Keep away from heat
            16: Keep away from sources of ignition - No smoking
            17: Keep away from combustible material
            18: Handle and open container with care
            20: When using, do not eat or drink
            21: When using, do not smoke
            22: Do not breathe dust
            23: Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
            24: Avoid contact with skin
            25: Avoid contact with eyes
            26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
            27: Take off immediately all contaminated clothing
            28: After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
            29: Do not empty into drains
            30: Never add water to this product
            33: Take precautionary measures against static discharges
            35: This material and its container must be disposed of in a safe way
            36: Wear suitable protective clothing
            37: Wear suitable gloves
            38: In case of insufficient ventilation, wear suitable respiratory equipment
            39: Wear eye/face protection
            40: To clean the floor and all objects contaminated by this material use ... (to be specified by the manufacturer)
            41: In case of fire and/or explosion do not breathe fumes
            42: During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified)
            43: In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
            45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
            46: If swallowed, seek medical advice immediately and show this container or label
            47: Keep at temperature not exceeding ... E C (to be specified by the manufacturer)
            48: Keep wetted with ... (appropriate material to be specified by the manufacturer)
            49: Keep only in the original container
            50: Do not mix with ... (to be specified by the manufacturer)
            51: Use only in well-ventilated areas
            52: Not recommended for interior use on large surface areas
            53: Avoid exposure - obtain special instruction before use
            56: Dispose of this material and its container to hazardous or special waste collection point
            57: Use appropriate container to avoid environmental contamination
            59: Refer to manufacturer/supplier for information on recovery/recycling
            60: This material and/or its container must be disposed of as hazardous waste
            61: Avoid release to the environment. Refer to special instructions safety data sheet
            62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label
            63: In case of accident by inhalation, remove casualty to fresh air and keep at rest
            64: If swallowed, rinse mouth with water (only if the person is conscious)

            Safety Phrases

            Combination of Safety Precautions

            1/2: Keep locked up and out of the reach of children
            3/7: Keep container tightly closed in a cool place
            3/9/14: Keep in a cool well-ventilated place away from ... (incompatible materials to be indicated by manufacturer)
            3/9/14/49: Keep only in the original container in a cool well-ventilated place away from ... (incompatible materials to be indicated by manufacturer)
            3/9/49: Keep only in the original container in a cool well-ventilated place
            3/14: Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer)
            7/8: Keep container tightly closed and dry
            7/9: Keep container tightly closed and in a well-ventilated place
            7/47: Keep container tightly closed and at a temperature not exceeding ... °C (to be specified by manufacturer)
            20/21: When using, do not eat, drink or smoke
            24/25: Avoid contact with skin and eyes
            27/28: After contact with skin, take off immediately all contaminated clothing and wash imediately with plenty of.... (to be specified by the manufacturer)
            29/35: Do not empty into drains, dispose of this container and it's material in a safe way
            29/56: Do not empty into drains, dispose of this material and its container to hazardous or special waste-collection point
            36/37: Wear suitable protective clothing and gloves
            36/37/39: Wear suitable protective clothing, gloves and eye/face protection
            36/39: Wear suitable protective clothing and eye/face protection
            37/39: Wear suitable gloves and eye/face protection
            47/49: Keep only in the original container at temperature not exceeding ... °C (to be specified by manufacturer)

            FLUKA BRAND F CODES

            F 1 Sensitive to air and humidity.
            F 2 Sensitive to air and CO2.
            F 3 Hygroscopic.
            F 4 Do not heat over …°C.
              1 = 10 °C
              2 = 20 °C
              3 = 30 °C
              4 = 40 °C
              5 = 50 °C
              6 = 60 °C
              7 = 70 °C
              8 = 80 °C
              9 = 90 °C
              10 = 100 °C
              11 = 110 °C
              12 = 120 °C
              13 = 130 °C
              14 = 140 °C
              15 = 150 °C

            F 5 Dry material may explode.
            F 6 Reacts with acids.
            F 7 Keep under CO2.
            F 8 Photosensitive.
            F 9 Keep under nitrogen.
            F 10 Keep under argon.
            F 11 Keep under inert gas.
            F 12 Shake before use.
            F 13 Malodorous.
            F 14 Carefully observe warning label.
            F 15 Limited shelf life.
            F 16 Decomposes easily.
            F 17 May decompose by explosion.
            F 18 Must be handled by instructed people only.
            F 19 Lachrymator.
            F 20 Not to be swallowed.
            F 21 Sensitive to humidity.
            F 22 Keep dust-free in the dark.
            F 23 Sensitive to air.
            F 24 Spontaneously flammable with alcohol.
            F 25 Keep under CO.
            F 26 Before distillation test for absence of peroxides.
            F 27 Cool before opening.
            F 28 May become cloudy (Polyformaldehyde).
            F 29 Spontaneously flammable when dry.
            F 30 Sediment unavoidable.
            F 31 Do not puncture.
            F 32 Avoid contact with heavy metal salts
                    especially iron salts.
            F 33 Causes fall in blood pressure.
            F 34 Sensitive to CO2.
            F 35 Narcotic effects.
            F 36 Extremely sensitive to air.

            PICTOGRAMS AND HAZARD CODES

            Biohazard B Biohazard   Highly Flammable or Extremely Flammable
            F  Highly Flammable
            F+  Extremely Flammable
              Oxidizing O Oxidizing
            Corrosive C Corrosive   Harmful or Harmful
            Xn Harmful
            Xi Irritant
            Radioactive R Radioactive
            Explosive E Explosive   Dangerous for the environment N
            Dangerous for the environment Toxic or Very Toxic
            T Toxic
            T+ Very Toxic

             

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